Ch10 The Chemical Bond - 1e- & 2e- Molecules

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Elements, Compounds, Mixtures

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“Empirical Evidence Supports Theoretical Knowledge”

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Levels of Organization

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Ch10 The Chemical Bond - 1e- & 2e- Molecules

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Born-Oppenheimer Approximation

Impact on H2 Hamiltonian

Definition

Molecular Orbital Theory & H2+

Pi Bond

Sigma Bond

MOs of H2

Bonding & Antibonding MOs for H2+

MOs are constructed from LCAOs

Exchange Integral, K

Columb Integra, J

Overlap Integral, S

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