Rearrangements

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Chemistry Chemistry is ultimately the study of matter including how it behaves and . Additionally in this unit we talked about how to describe properties and changes using diagrams and nomenclature, and equations.

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Reduction of ketone

Johnson

- cyclization of carboxylic acid to cyclic ketone

Saucy-Marbet

- rearrangement

- synthesis of Grignard-reagent

- treatment with Grignard-reagent of aldehyde

- cyclization of product to alkyl-laktone

- reduction of aldehyde with NaBH4

- cyclization of second OH to lactone

Ireland

- acylation and purification

- LDA synthesis and actual rearrangement

- purification

- cyclization of (alkyl) carboxylic acid to alkylated cyclic ketone

ester hydrolysis